The short version
Vitamin E is the umbrella name for eight related fat-soluble compounds, though only one form, alpha-tocopherol, is the one the body actually maintains in blood.
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Vitamin E is the collective name for a group of fat-soluble compounds with distinctive antioxidant activities
It works chiefly as an antioxidant, protecting cell membranes from the wear of ordinary metabolism, and it also plays a supporting role in immune function.
The food list runs through the plant aisle
NIH's own ranking of sources is blunt about where vitamin E actually comes from.
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Nuts, seeds, and vegetable oils are among the best sources of alpha-tocopherol, and significant amounts are available in green leafy vegetables and fortified cereals
An ounce of almonds supplies close to half a day's Daily Value, sunflower seeds a bit more, and a tablespoon of wheat germ oil clears it outright. Spinach and other leafy greens add smaller but real amounts on top.
Who actually falls short
One honest wrinkle before the reassurance: national dietary surveys have found a real gap between typical intake and the RDA, and it has nothing to do with going vegan.
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the diets of most Americans provide less than the RDA levels of vitamin E
That gap shows up across the general population, not in vegans specifically, and the federal researchers note it may be overstated because cooking fats are hard to track. Separately, actual deficiency disease looks nothing like a simple shortfall.
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Frank vitamin E deficiency is rare and overt deficiency symptoms have not been found in healthy people who obtain little vitamin E from their diets
Where deficiency does show up, it is almost always an absorption problem rather than a food choice.
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people with fat-malabsorption disorders are more likely to become deficient than people without such disorders
People with conditions such as Crohn's disease or cystic fibrosis are the group actually at risk, not people eating a lower-fat, plant-based diet. High-dose supplements carry a separate caution in the other direction: large trials have linked long-term high doses to a small rise in all-cause mortality and, in one trial of older men, a higher rate of prostate cancer, which is a reason to get vitamin E from food rather than from a megadose pill.

